See /usr/share/postfix/main.cf.dist for a commented, more complete version
Debian specific: Specifying a file name will cause the first
line of that file to be used as the name. The Debian default
is /etc/mailname.
#myorigin = /etc/mailname
smtpd_banner = $myhostname ESMTP $mail_name (Ubuntu)
biff = no
appending .domain is the MUA’s job.
append_dot_mydomain = no
Uncomment the next line to generate “delayed mail” warnings
#delay_warning_time = 4h
readme_directory = no
TLS parameters
smtpd_tls_cert_file=/etc/ssl/certs/ssl-cert-snakeoil.pem
smtpd_tls_key_file=/etc/ssl/private/ssl-cert-snakeoil.key
smtpd_use_tls=yes
smtpd_tls_session_cache_database = btree:${data_directory}/smtpd_scache
smtp_tls_session_cache_database = btree:${data_directory}/smtp_scache
See /usr/share/doc/postfix/TLS_README.gz in the postfix-doc package for
information on enabling SSL in the smtp client.
myhostname = xeo.me
alias_maps = hash:/etc/aliases
alias_database = hash:/etc/aliases
#myorigin = /etc/mailname
mydestination = def.eu, abc.me, localhost.me, localhost
relayhost =
mynetworks = 127.0.0.0/8 [::ffff:127.0.0.0]/104 [::1]/128
mailbox_size_limit = 0
recipient_delimiter = +
inet_interfaces = all
inet_protocols = all
virtual_alias_maps = hash:/etc/postfix/virtual
mailbox_command = /usr/bin/procmail-wrapper -o -a $DOMAIN -d $LOGNAME
smtpd_sasl_authenticated_header = yes
Btw, the What domain to use in outbound mail is being set to “Use hostname” and this:
Send outgoing mail via host
makes me wonder, since the radio button for “Deliver directly” is not being set, but the other one without any host named. So i will give it a try with “Deliver directly”. I know, why mail servers always give me headaches 
Update: I set it to “Deliver directly” and changed the line with mydetination to:
mydestination = $myhostname, localhost.$mydomain, localhost
Now i can send mails from Webmin and get them. I can also answer them, but i still see this line in mail.log:
Mar 13 09:08:22 abc postfix/local[32546]: 6FB092742306: to=, orig_to=, relay=local, delay=22, delays=0.09/0.03/0/22, dsn=2.0.0, status=sent (delivered to command: /usr/bin/procmail-wrapper -o -a $DOMAIN -d $LOGNAME) Mar 13 09:08:22 abc postfix/qmgr[1961]: 6FB092742306: removed
and therefore it won’t be in user’s mailbox.
Found also this:
smtpd_sasl_auth_enable = yes
smtpd_sasl_security_options = noanonymous
broken_sasl_auth_clients = yes
smtpd_recipient_restrictions = permit_mynetworks permit_sasl_authenticated reject_unauth_destination check_policy_service inet:127.0.0.1:10023
smtpd_tls_cert_file = /etc/postfix/postfix.cert.pem
smtpd_tls_key_file = /etc/postfix/postfix.key.pem
smtpd_tls_security_level = may
smtpd_tls_mandatory_ciphers = high
Would this do the trick with Outlook?